ICARUS Chamber Experiment: Nguyen Group_20220523_alpha-Pinene/Ammonium Sulfate/Ozone/Hydrogen Peroxide_Ozone_Ammonium sulfate

d789105
| DOI: 10.5065/7QR5-3Y28
 
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Abstract:

Goals:
To quantify SOA yield and gas-phase product yields from humid ozonolysis of a-pinene, which will serve as a "control" experiment to subtract the ozonolysis contribution to the nighttime chemistry of a-pinene as measured in the experiment on 5/20/22.

Summary:
The chamber was humidified, after which H2O2, and O3 were injected in the chamber and allowed to equilibrate. Ammonium sulfate seed particles were injected. Then a-pinene was injected and decayed by reaction with ozone (plus some contribution from OH). Gas phase organics were monitored by CF3O- CIMS (units: normalized counts), particle formation was monitored by SMPS, and RH, T, O3, NOx were monitored throughout.

O3/NOx data sometimes require post-correction not applied here, including subtraction of an ozone interference from H2O2 (1 ppm H2O2 is detected as about 12 ppb ozone) and correction for an in-line HEPA filter (see timeline for applicable timing) that scrubs about 10% of NO2 and 45% of ozone.

CIMS ran out of reagent at about 14:30.

Organization: Nguyen Group
Lab Affiliation: UC Davis
Chamber: Tran's big bag of air

Experiment Category: Gas phase chemical reaction, Aerosol formation
Oxidant: Ozone
Reactants: alpha-Pinene, Ammonium Sulfate, Ozone, Hydrogen Peroxide
Reaction Type: Dark oxidation
Relative Humidity: 63
Temperature: 22
Seed Name: Ammonium sulfate
Pressure: ~1 atm

Temporal Range:
2022-05-23
Variables:
Trace Gases/Trace Species
Data Types:
Platform Observation
Data Contributors:
UC-DAVIS/CHEMISTRY
Department of Chemistry, University of California, Davis
Related Resources:
Icarus Dataset at UC-Davis
Total Volume:
0.19 MB
Data Formats:
ASCII (see dataset documentation)
Metadata Record:
Data License:
Data LicenseThis work is licensed under a Creative Commons Attribution 4.0 International License.
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