ICARUS Chamber Experiment: Jimenez Lab_20170125_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Oleic Acid_15.6_ug/m3_OA1

d789021
| DOI: 10.5065/P8YE-FR60
 
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Abstract:

Goals:
Fast burst photooxidation of alkanols (high-NOx). Gas-aerosol-wall partitioning kinetics. Determine accommodation coefficient (alpha) and effective volatility under differing seed aerosol types (differing phase and polarities, inorganic/organic, humid/dry, standards/SOA).

Summary:
Alkanols, Methyl nitrite, NO, and particle seed added to chamber, UV lights turned on for 10 sec, multifunctional products formed. In most experiments in this experimental set, 10 s^-1 UV light/photochemistry burst repeated a few times. SMPS measurements of particle size distributions were conducted to determine particle formation, surface area and condensational sink rate coefficients.
Gas-phase chemical species were measured with nitrate CIMS.

Organization: Jimenez Lab
Lab Affiliation: University of Colorado, Boulder
Chamber: 1-White (1W)

Experiment Category: Volatility and partitioning
Oxidant: Hydroxyl radical
Reactants: 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL
Reaction Type: Photooxidation
Relative Humidity: < 1
Temperature: 25
Seed Name: Oleic Acid

Temporal Range:
2017-01-25
Variables:
Trace Gases/Trace Species
Data Types:
Platform Observation
Data Contributors:
CU-Boulder/CHEMISTRY
Chemistry, University of Colorado, Boulder
Related Resources:
ICARUS Dataset at UC-Davis
Total Volume:
2.46 MB
Data Formats:
ASCII (see dataset documentation)
Metadata Record:
Data License:
Data LicenseThis work is licensed under a Creative Commons Attribution 4.0 International License.
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